Friday, September 24, 2010

Periodicity of chemical properties

The main value of the periodic table is the ability to predict the chemical properties of an element based on its location on the table. It should be noted that the properties vary differently when moving vertically along the columns of the table than when moving horizontally along the rows.

Trends of groups

Modern quantum mechanical theories of atomic structure explain group trends by proposing that elements within the same group have the same electron configurations in their valence shell, which is the most important factor in accounting for their similar properties. Elements in the same group also show patterns in their atomic radius, ionization energy, and electronegativity. From top to bottom in a group, the atomic radii of the elements increase. Since there are more filled energy levels, valence electrons are found farther from the nucleus. From the top, each successive element has a lower ionization energy because it is easier to remove an electron since the atoms are less tightly bound. Similarly, a group will also see a top to bottom decrease in electronegativity due to an increasing distance between valence electrons and the nucleus.

Trends of periods

Periodic trend for ionization energy. Each period begins at a minimum for the alkali metals, and ends at a maximum for the noble gases.
Elements in the same period show trends in atomic radius, ionization energy, electron affinity, and electronegativity. Moving left to right across a period, atomic radius usually decreases. This occurs because each successive element has an added proton and electron which causes the electron to be drawn closer to the nucleus. This decrease in atomic radius also causes the ionization energy to increase when moving from left to right across a period. The more tightly bound an element is, the more energy is required to remove an electron. Similarly, electronegativity will increase in the same manner as ionization energy because of the amount of pull that is exerted on the electrons by the nucleus. Electron affinity also shows a slight trend across a period. Metals (left side of a period) generally have a lower electron affinity than nonmetals (right side of a period) with the exception of the noble gases.

Periodic Table Of Elements

The periodic table of the chemical elements (also periodic table of the elements or just the periodic table) is a tabular display of the chemical elements. Although precursors to this table exist, its invention is generally credited to Russian chemist Dmitri Mendeleev in 1869, who intended the table to illustrate recurring ("periodic") trends in the properties of the elements. The layout of the table has been refined and extended over time, as new elements have been discovered, and new theoretical models have been developed to explain chemical behavior.[1]
The periodic table is now ubiquitous within the academic discipline of chemistry, providing a useful framework to classify, systematize, and compare all of the many different forms of chemical behavior. The table has found many applications in chemistry, physics, biology, and engineering, especially chemical engineering. The current standard table contains 118 elements to date. (elements 1118)

Thursday, September 23, 2010

History of Chemistry

Chemistry is a branch of science that has been around for a long time. In fact, chemistry is known to date back to as far as the prehistoric times. Due to the amount of time chemistry takes up on the timeline, the science is split into four general chronological categories. The four categories are: prehistoric times - beginning of the Christian era (black magic), beginning of the Christian era - end of 17th century (alchemy), end of 17th century - mid 19th century (traditional chemistry) and mid 19th century - present (modern chemistry)